Effect of heat treatment on the structural, morphology and electrochemical performance of perovskite Ba0.5Sr0.5Co0.8Fe0.2O3−δ-Sm0.2Ce0.8O1.9 carbonate protective coating for SOFC metallic interconnect

Tan, Kang Huai and Hamimah Abd.Rahman, and Hariati Mohd Taib, (2020) Effect of heat treatment on the structural, morphology and electrochemical performance of perovskite Ba0.5Sr0.5Co0.8Fe0.2O3−δ-Sm0.2Ce0.8O1.9 carbonate protective coating for SOFC metallic interconnect. Jurnal Kejuruteraan, 32 (4). pp. 637-644. ISSN 0128-0198

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Official URL: https://www.ukm.my/jkukm/volume-324-2020/

Abstract

A composite perovskite Ba0.5Sr0.5Co0.8Fe0.2O3−δ-Sm0.2Ce0.8O1.9 carbonate (BSCF-SDCC) coating was investigated to enhance the performance of SUS 430 stainless steel as interconnect material for solid oxide fuel cells (SOFCs). BSCF-SDCC powder was successfully obtained by low-speed wet milling method from commercial BSCF, SDC, and binary carbonates. The developed BSCF-SDCC powder were heat-treated 600 °C for 90 min, and then characterized by X-ray diffraction (XRD) and field-emission scanning electron microscopy (FESEM) equipped with energy-dispersive spectroscopy (EDS). FESEM revealed better morphology of BSCF-SDCC powder with heat treatment. However, XRD analysis showed the destruction of BSCF phase in the BSCF-SDCC powder after heat treatment at 600 °C. Moreover, electrophoretic deposition (EPD) of BSCF-SDCC powder in an ethanol-added dispersing agent suspension was investigated under 10 volt 10 minutes by 10 g/l. The coated samples were then heat-treated at 600 °C. The coated samples were characterized by comparing between the samples with and without heat treatment based on XRD, SEM-EDS, and area specific resistance (ASR) analyses. XRD analysis indicated BSCF phases disappeared for the samples with heat treatment. The heat-treated sample performed better coating morphology and fewer pores. The samples underwent 500 hours of air oxidation at 600°C, and ASR was measured by DC 2-point method during in situ oxidation process. The coated sample with heat treatment at 600 °C exhibited excellent low area-specific resistance reading of below 0.1 Ωcm2, which is an essential requirement for interconnect materials. After 500 h of oxidation, the XRD patterns revealed stable phase and maintained good coating morphology.

Item Type:Article
Keywords:Ba0.5Sr0.5Co0.8Fe0.2O3−δ; Electrophoretic deposition; Interconnect; Perovskite coating; Solid oxide fuel cell
Journal:Jurnal Kejuruteraan
ID Code:17201
Deposited By: ms aida -
Deposited On:26 Jul 2021 03:13
Last Modified:27 Jul 2021 02:27

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