Spectrophotometric determination of mercury with iodide and rhodamine B (Penentuan spektrofotometri untuk merkuri dengan menggunakan Rhodamine B dan Iodida)

Au, Yoong Yow Loo and Yap, Pei Lay and Muralithran G. Kutty, and Olaf Timpe, (2012) Spectrophotometric determination of mercury with iodide and rhodamine B (Penentuan spektrofotometri untuk merkuri dengan menggunakan Rhodamine B dan Iodida). Sains Malaysiana, 41 (2). pp. 213-218. ISSN 0126-6039

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Abstract

Spectrophotometric methods for the trace amount determination of Hg(II) via extraction and polyvinylalcohol (PVAl) water stabilization was explored. The methods are based on the formation of ion-association complex of Hg(II) with Rhodamine B, [(HgI4)2-][(Rhodamine B)+]2 in highly acidic solution. Extraction using benzene showed the Beer’s law was obeyed for mercury(II) in the range of 5 to 27 μg Hg(II) / 20 mL of sample and molar absorptivity, ε = 17.68 × 104 L mole-1cm-1. For polyvinylalcohol (PVAl) stabilization method, Beer’s law showed the validity range of 10 to 120 μg Hg(II) / 10 mL of sample and molar absorptivity, ε = 16.84 × 103 L mole-1cm-1. The benzene-extraction method has been applied in assessing the performance of copper sulfide ion-exchanger in removing Hg(II). The result was comparable to the result obtained using cold vapor atomic absorption spectrometry (CVAAS).

Item Type:Article
Keywords:Aqueous mercury analysis; Hg complexation; Rhodamine B; UV-Visible spectrophotometry
Journal:Sains Malaysiana
ID Code:3293
Deposited By: Mr Azam
Deposited On:12 Jan 2012 03:44
Last Modified:14 Dec 2016 06:34

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