Au, Yoong Yow Loo and Yap, Pei Lay and Muralithran G. Kutty, and Olaf Timpe, (2012) Spectrophotometric determination of mercury with iodide and rhodamine B (Penentuan spektrofotometri untuk merkuri dengan menggunakan Rhodamine B dan Iodida). Sains Malaysiana, 41 (2). pp. 213-218. ISSN 0126-6039
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Official URL: http://www.ukm.my/jsm/
Abstract
Spectrophotometric methods for the trace amount determination of Hg(II) via extraction and polyvinylalcohol (PVAl) water stabilization was explored. The methods are based on the formation of ion-association complex of Hg(II) with Rhodamine B, [(HgI4)2-][(Rhodamine B)+]2 in highly acidic solution. Extraction using benzene showed the Beer’s law was obeyed for mercury(II) in the range of 5 to 27 μg Hg(II) / 20 mL of sample and molar absorptivity, ε = 17.68 × 104 L mole-1cm-1. For polyvinylalcohol (PVAl) stabilization method, Beer’s law showed the validity range of 10 to 120 μg Hg(II) / 10 mL of sample and molar absorptivity, ε = 16.84 × 103 L mole-1cm-1. The benzene-extraction method has been applied in assessing the performance of copper sulfide ion-exchanger in removing Hg(II). The result was comparable to the result obtained using cold vapor atomic absorption spectrometry (CVAAS).
Item Type: | Article |
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Keywords: | Aqueous mercury analysis; Hg complexation; Rhodamine B; UV-Visible spectrophotometry |
Journal: | Sains Malaysiana |
ID Code: | 3293 |
Deposited By: | Mr Azam |
Deposited On: | 12 Jan 2012 03:44 |
Last Modified: | 14 Dec 2016 06:34 |
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